LUDWIG BOLTZMANN: BIOGRAPHY AND CONTRIBUTIONS - SCIENCE - 2024

Ludwig Boltzmann (1844-1906) was an Austrian scientist considered the father of statistical mechanics. His contributions in the field of science were various; Boltzmann's equation and principle, statistical mechanics or the H.

For his contributions and pioneering ideas, his surname is widely known, not only among the scientific community, but also by society in general. There are even several artistic works and monuments in his honor that celebrate his contributions.

Portrait of the scientist Ludwig Boltzmann

Boltzmann's work complemented scientific work of great importance, such as those carried out by Maxwell. Their contributions even had a wide influence on the work carried out by Albert Einstein.

Boltzmann's works developed mainly in physics, however he also published works related to other fields such as the life sciences and the philosophy of science.

Biography

Ludwig Boltzmann was born on February 20, 1844 in Austria, in the city of Vienna. At that time, this area was part of the Austro-Hungarian Empire. Ludwig's family was characterized by being wealthy, which allowed him to have the possibility of having a good education.

In addition to his family assets, Ludwig also had a modest fortune inherited from his grandfather; This helped him pay for his studies without having any difficulties.

At 15, Ludwig was orphaned, so this inheritance from his grandfather served him even more after being left without a father at a young age.

Studies

Boltzmann's first training was in the city of Linz, in northern Austria, where the family had moved.

Historical records have been able to show that, since childhood, Ludwig Boltzmann was characterized by being extremely curious, in addition to being very interested in learning, with great ambition and, at times, with restless and anxious attitudes.

Later he entered the University of Vienna, where he received teachings from illustrious figures such as the physicist Josef Stephan, the mathematician József Miksa Petzval and the physicist and mathematician Andreas von Ettingshausen.

He graduated from this university in 1866; the tutor of Boltzmann's doctoral thesis was precisely Josef Stephan, with whom he later worked. This work with Stephan lasted 3 years, from 1867 to 1869, and at that time they focused on analyzing the energy losses experienced by hot elements.

Teaching stage

Beginning in 1869, Ludwig Boltzmann dedicated himself to teaching at the University of Graz, the second largest university in Austria. At that university he gave classes in theoretical physics. Parallel to this, Boltzmann continued his training in the German cities of Berlin and Heidelberg.

Boltzmann taught at the University of Graz until 1873, the year in which he began teaching mathematics at the University of Vienna. He returned to Graz three years later, in 1876, at which time he was already recognized in the field of science as a result of a series of published works and various investigations.

Maxwell-Boltzmann statistic

One of the most outstanding investigations of that time was the Maxwell-Boltzmann statistic, developed by him and Maxwell in 1871.

During 1894 he returned to the University of Vienna to work as a professor of theoretical physics. At that time Boltzmann was forced to interact with Ernst Mach, a physicist and philosopher with whom Boltzmann had profound differences.

So many were the problems that existed between these two scientists, that Boltzmann decided to go to Leipzig to avoid being in contact with Mach.

Ernst Mach left his teaching work at the University of Vienna in 1901 for health reasons; therefore, Boltzmann returned in 1902 and not only obtained again the option of teaching theoretical physics classes, but also took the reins of the chair of history and philosophy of science, a subject previously taught by Mach.

Hypothesis about the atom

Upon his return to the University of Vienna, Boltzmann began to make public his support for the hypothesis of the existence of the atom. This consideration was widely criticized by the scientific community; Among the staunchest critics was Ernst Mach.

The constant criticism he received for his work had a very unfavorable effect on Boltzmann, who according to historical records does not appear to have had a calm character.

Rather, Boltzmann seems to have been a man of intense and extreme reactions, being able to prove to be outgoing and sympathetic and, on other occasions, very introverted and prone to depression.

One of the most criticized aspects of Boltzmann's statements was that this scientist determined that the second law of thermodynamics, related to entropy, was essentially statistical in nature.

This fact implied that various scenarios could be generated as a result of oscillations, which would give rise to results that were not foreseen in this law.

Critics of Boltzmann indicated that it did not make sense to link the statistical field with the laws of thermodynamics, since they considered that the laws were absolute questions, and could not accept that this fundamental law had variable characteristics.

Death

The pressure as a result of the strong and constant criticism made of Boltzmann made him decide to take his own life. In 1906 he was on vacation with his family in the town of Duino, located very close to Trieste.

While his wife and children were at sea, enjoying the holidays, Ludwig Boltzmann hanged himself at the summer home.

Causes

Various historians have determined that the causes of his suicide were closely related to the fact that the scientific community did not recognize his research as true.

Boltzmann is said to have a clear and marked commitment to the truth. Part of what affected him the most was the fact that he had found a truth about the existence of the atom, and witnessed how the society of his time did not value this discovery, which he anticipated could be essential for the current generation and for many future generations.

The fact that tradition was more important in the framework of a society, rather than innovations derived from new concepts transcendental for the time, caused Botlzmann to become depressed.

Other historians indicate that the causes of Boltzmann's death also included other elements, since this scientist had certain traits that denoted instability and imbalance in many of his actions.

Shortly after his death, members of this scientific community began to generate evidence that corroborated the concepts developed by Boltzmann, at the same time that they earned him scientific recognition for his contributions. This happened just two years after Boltzmann died.

It was specifically the studies of the chemist-physicist Jean Perrin that confirmed the veracity of Boltzmann's constant, named after the scientist, which links energy with absolute temperature. This was enough to convince the scientific community of the existence of atoms.

Main contributions

Boltzmann's equation

Ludwig Boltzmann's most recognized contribution is the approach to the equation that bears his name: The Boltzmann equation. This equation was originally proposed in 1870 and later underwent some developments.

The equation, based on the notions of atoms and molecules, defined the probability of finding the molecules in a given state.

With further development, the equation became useful for calculating the potential equilibrium in ion species and for describing conformational changes of biological molecules.

Statistical mechanics

Some authors claim that Boltzmann was the first person to truly apply statistics in the study of gases.

Thanks to this, they consider that kinetic theory studies became studies of statistical mechanics.

For this contribution, Boltzmann is recognized by many as the father of statistical mechanics.

This discipline has made it possible to study the properties of macroscopic materials and objects from the properties of their atoms and molecules.

Entropy and Boltzmann's principle

Although the concept of entropy had been introduced by Rudolf Clausius in 1865, Boltzmann brought the notion of entropy into everyday life.

In 1877 Boltzmann indicated that entropy is a measure of the disorder of the state of a physical system.

Under this concept, Boltzmann formulated an equation for entropy known as Boltzmann's principle.

Philosophy of science

Boltzmann's contributions to the development of the philosophy of science are also widely recognized.

Many of his ideas in this field were collected in his text "Popular Writings" published in 1905.

Boltzmann treated very varied philosophical topics within science. Among them he discussed terms such as realism and idealism. I also criticize renowned philosophers such as Kant and Hegel.

Boltzmann firmly believed that philosophy could help science not ask useless questions. For this reason, Boltzmann referred to himself as a realist, although many others identified him as belonging to the materialist current.

References

1. Brown HR Myrvold W. Uffink J. Boltzmann's H-theorem, its discontents, and the birth of statistical mechanics. Studies in History and Philosophy of Modern Physics. 2009; 40 (2): 174–191.
2. Dubois J. Ouanounou G. Rouzaire-Dubois B. The Boltzmann equation in molecular biology. Progress in Biophysics and Molecular Biology. 2009; 99 (2): 87–93.
3. Flamm D. Ludwig Boltzmann and his influence on science. Studies in History and Philosophy of Science. 1983; 14 (4): 255–278.
4. Science AA A Monument for Ludwig Boltzmann. Science, New Series. 1932 75 (1944).
5. Swendsen RH Footnotes to the history of statistical mechanics: In Boltzmann's words. Physica A: Statistical Mechanics and Its Applications. 2010; 389 (15), 2898-2901.
6. Williams MMR Ludwig Boltzmann. Annals of Nuclear Energy. 1977; 4 (4–5): 145–159.